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⚑ Mass Number, Atomic Number and Isotopes

Spec 6.4.1.2 πŸ“™ Higher
πŸ“– In-Depth Theory

Atomic Number and Mass Number

ATOMIC NUMBER (Z) = number of PROTONS in the nucleus.
Defines the element β€” all atoms of the same element have the same atomic number.
In a neutral atom: atomic number = number of electrons.
MASS NUMBER (A) = total number of PROTONS + NEUTRONS.
Also called nucleon number.
Number of neutrons = mass number βˆ’ atomic number = A βˆ’ Z
NUCLEAR NOTATION:
₍Zβ‚ŽA X
Where X = element symbol, A = mass number (top), Z = atomic number (bottom).
EXAMPLES:
¹²₆C β€” carbon: 6 protons, 6 neutrons, 6 electrons
²³₁₁Na β€” sodium: 11 protons, 12 neutrons, 11 electrons
²³⁡₉₂U β€” uranium: 92 protons, 143 neutrons, 92 electrons

Isotopes

ISOTOPES are atoms of the same element with the SAME atomic number but DIFFERENT mass numbers.
Same element β†’ same number of protons.
Different mass numbers β†’ different numbers of NEUTRONS.
EXAMPLES:
Carbon isotopes:
ΒΉΒ²C β€” 6 protons, 6 neutrons (most common, stable)
ΒΉΒ³C β€” 6 protons, 7 neutrons (stable, rare)
¹⁴C β€” 6 protons, 8 neutrons (radioactive β€” used in carbon dating)
Hydrogen isotopes:
ΒΉH β€” 1 proton, 0 neutrons (protium β€” most common)
Β²H β€” 1 proton, 1 neutron (deuterium)
Β³H β€” 1 proton, 2 neutrons (tritium β€” radioactive)
CHEMICAL PROPERTIES:
Isotopes of the same element have the SAME chemical properties β€” same electron arrangement.
Physical properties differ slightly (different mass β†’ different density, melting point etc.).
SOME ISOTOPES ARE RADIOACTIVE (unstable nucleus) β€” they undergo radioactive decay.

Ions

When atoms GAIN or LOSE electrons they become IONS.
POSITIVE ION (CATION): loses electrons β†’ more protons than electrons β†’ positive charge.
NEGATIVE ION (ANION): gains electrons β†’ more electrons than protons β†’ negative charge.
Example:
Sodium atom ²³₁₁Na: 11 protons, 11 electrons β€” neutral.
Sodium ion Na⁺: 11 protons, 10 electrons β€” lost 1 electron β†’ charge +1.
Fluorine atom ¹⁹₉F: 9 protons, 9 electrons β€” neutral.
Fluoride ion F⁻: 9 protons, 10 electrons β€” gained 1 electron β†’ charge βˆ’1.
Note: NUCLEAR NOTATION and mass number / atomic number are NOT changed by ion formation β€” only the electron count changes.
⚠️ Common Mistake

Mass number is protons + NEUTRONS β€” not protons alone. To find neutrons: subtract atomic number FROM mass number. Isotopes have the same atomic number (same element) but different mass numbers (different neutron counts).

πŸ“ Key Equations
Number of neutrons = mass number βˆ’ atomic number
πŸ“Œ Key Note

Atomic number (Z) = protons. Mass number (A) = protons + neutrons. Neutrons = A βˆ’ Z. Isotopes: same Z, different A (different neutron count). Same chemical properties, different physical. Some isotopes radioactive. Ions: gain/lose electrons β€” mass number unchanged.

🎯 Matching Activity β€” Nuclear Notation

Match each nucleus to its correct particle count. β€” drag the symbols on the right to match the component names on the left.

¹²₆C
Drop here
²³₁₁Na
Drop here
¹⁴C (isotope of ¹²C)
Drop here
Na⁺ ion
Drop here
6 protons, 8 neutrons β€” same element, different neutron count
11 protons, 12 neutrons, 11 electrons (neutral atom)
6 protons, 6 neutrons, 6 electrons (neutral atom)
11 protons, 10 electrons β€” lost 1 electron, charge +1
⚽ FIFA Worked Examples
Particle Counts

An atom has nuclear notation ³⁡₁₇Cl. How many protons, neutrons and electrons does it have?

F

Protons = atomic number (Z); Neutrons = A βˆ’ Z; Electrons = protons (neutral atom)

I

A = 35, Z = 17

F

Protons = 17; Neutrons = 35 βˆ’ 17 = 18; Electrons = 17

A

17 protons, 18 neutrons, 17 electrons

🎯 Test Yourself
Question 1 of 2
1. An atom has 17 protons and mass number 35. How many neutrons does it have?
2. Two atoms have the same atomic number but different mass numbers. What are they?
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