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AQA Chemistry 5.4.2.1–5.4.2.2

Reactions of acids with metals and bases

Every reaction makes a salt. What else it makes depends on what the acid meets. Pick an acid and a reactant, and predict before it runs.

Start here

A tablet in vinegar.

Drop an indigestion tablet into a glass of vinegar and watch it closely.

If you had to guess, does it give off a gas, or just quietly dissolve?

Predict, then run

What does the acid meet?

Acids produce hydrogen ions, H+, in water. Metal oxides and hydroxides are bases: they neutralise acids. An alkali is a base that dissolves in water. Choose an acid and a reactant, then predict the products.

Predict the products.

The four reactions

The salt comes from the metal and the acid.

Hydrochloric acid makes chlorides, sulfuric acid makes sulfates, nitric acid makes nitrates. The reactions with oxides, hydroxides and carbonates are all neutralisation. Only metals above hydrogen in the reactivity series react with dilute acids: copper doesn’t.

Formulae of salts

Balance the charges.

A salt has no overall charge. Take enough of each ion for the charges to cancel. Mg2+ needs two Cl−, so magnesium chloride is MgCl2. Two Na+ balance one SO42−, so sodium sulfate is Na2SO4. Now you.

Zinc chloride

Zn²⁺ and Cl⁻

Potassium sulfate

K⁺ and SO4²⁻

Calcium nitrate

Ca²⁺ and NO3⁻

Think again · where does the fizz come from?

“Acid and a carbonate make a salt and water.”

Your call

Choose

Calcium carbonate is added to hydrochloric acid. Which list gives all the products?

Sort

Which products?

Place each reactant with what it makes with an acid.

Tap a card, then tap the box it belongs in. Tap a placed card to take it back.

Command words in this lesson

Name
The salt: metal first, then chloride, sulfate or nitrate.
Write
The formula, with charges balanced.
Describe
A test: what you do, and what you see.

Key fact

Acid + metal gives a salt and hydrogen. Acid + metal oxide or hydroxide gives a salt and water. Acid + carbonate gives a salt, water and carbon dioxide.

Key note · AQA 5.4.2.1–5.4.2.2

Reactions of acids

  1. Acids produce H⁺ ions in water. Bases (metal oxides and hydroxides) neutralise acids; alkalis are soluble bases.
  2. Acid + metal → salt + hydrogen (metals above hydrogen only; copper doesn’t react). Test: lit splint, squeaky pop.
  3. Acid + metal oxide or hydroxide → salt + water. Acid + carbonate → salt + water + carbon dioxide. Test: limewater milky. All three are neutralisation.
  4. Hydrochloric → chlorides; sulfuric → sulfates; nitric → nitrates.
  5. Salt formulae: balance the ion charges, e.g. Mg²⁺ + 2Cl⁻ → MgCl2.

Photograph this card. Tomorrow, cover it and say each line first.

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