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AQA Chemistry 5.4.1.1, 5.4.1.3 (+ 5.4.1.4 Higher) · Combined and Triple

Oxidation and reduction

Oxidation is gaining oxygen; reduction is losing it, and one never happens without the other.

Start here

A rusty gate.

An iron gate left out in the weather goes rusty and flaky.

If you had to guess, has the iron gained something from the air, or lost something to it?

In terms of oxygen

Who gained it, who lost it.

Oxidation is the gain of oxygen; reduction is the loss of oxygen. A reaction in which both happen is called a redox reaction. Watch the oxygen move from copper oxide to hydrogen.

For each reactant, oxidised or reduced? The equations are balanced; check them as you go.

2Mg + O2 → 2MgO

Magnesium

Gained or lost oxygen?

CuO + H2 → Cu + H2O

Copper oxide

Gained or lost oxygen?

CuO + H2 → Cu + H2O

Hydrogen

Gained or lost oxygen?

2CuO + C → 2Cu + CO2

Copper oxide

Gained or lost oxygen?

2CuO + C → 2Cu + CO2

Carbon

Gained or lost oxygen?

Metals less reactive than carbon can be extracted from their oxides by reduction with carbon: Extraction of metals.

Think again · the extractor

“Carbon is reduced when it takes the oxygen off a metal oxide.”

Your call

Choose

2CuO + C → 2Cu + CO2. What happens to the carbon?

Sort

Oxidised or reduced?

Use the oxygen definitions.

Tap a card, then tap the box it belongs in. Tap a placed card to take it back.

Command words in this lesson

Identify
Which substance is oxidised and which is reduced, from a given equation.
Explain
Why, in terms of oxygen.

Key fact

Oxidation is the gain of oxygen; reduction is the loss of oxygen. They always happen together.

Key note · AQA 5.4.1.1, 5.4.1.3 (+ 5.4.1.4 HT) · Combined and Triple

Oxidation and reduction

  1. Oxidation is the gain of oxygen; reduction is the loss of oxygen. They occur together: in CuO + H2 → Cu + H2O, copper oxide is reduced and hydrogen is oxidised.
  2. Metals react with oxygen to form metal oxides; the metal is oxidised (2Mg + O2 → 2MgO). Carbon reduces the oxides of less reactive metals (2CuO + C → 2Cu + CO2): the oxide is reduced, the carbon oxidised.
  3. Equations must balance. Chlorine and oxygen are Cl2 and O2.

Photograph this card. Tomorrow, cover it and say each line first.

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