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AQA Chemistry (8462) 4.3.3.1 · Quantitative

Percentage yield

The equation says you can make 8.0 g. The balance says you made 6.2 g. Where did the rest go, and how do you put a number on the gap?

Start here

8.0 g on paper. 6.2 g in the dish.

A student makes copper sulfate crystals from copper oxide and sulfuric acid. From the balanced equation, the reactants they used can make 8.0 g at most. After filtering, crystallising and drying, the balance reads 6.2 g.

If you had to guess, was the missing 1.8 g destroyed in the reaction, or left behind along the way?

The yield bench · Required practical 1, making a salt

Follow 8.0 g of copper sulfate through the practical.

0 of 5 steps run

React

Warm the dilute sulfuric acid and stir in copper oxide until no more dissolves. The black powder left over is the excess.

Commit first. Does any copper sulfate leave the product at this step?

Copper sulfate in the product8.0 g of 8.0 g

Think again · weighing

“My yield came out at 108%. My technique must be better than perfect.”

Spot the flaw

Suggest

The working is right: 8.64 g weighed, 8.0 g maximum. Suggest why the percentage yield is over 100%.

Sort the reasons

Less product, faster product, or impossible?

Place each statement.

Tap a card, then tap the box it belongs in. Tap a placed card to take it back.

Manufacturers want a high yield. A low yield wastes raw materials, which raises costs, and the wasted reactants become waste the factory has to deal with. Many raw materials are finite, so less waste is more sustainable. In the Haber process only about 15% of the nitrogen and hydrogen becomes ammonia on each pass, so the unreacted gases are recycled, raising the overall yield to about 98%.

Commit first

Calculate

Theoretical yield 8.0 g, actual yield 6.2 g. Which working gives the percentage yield?

Equation

Learn it · chemistry has no equation sheet

Percentage yield (%) = (actual yield ÷ theoretical yield) × 100

Both yields in the same unit before you divide.

Command words in this lesson

Calculate
Convert, formula, insert, fine-tune, answer. The answer carries the % sign.
Give
A reason in a few words, no explanation needed: one mark each.
Suggest
Apply what you know to the practical in front of you: where was product lost, or what else was weighed?
Explain
Link a cause to its effect on the mass collected, with "so".

Key note · AQA 4.3.3.1 (chemistry only)

Percentage yield

  1. % yield = (actual ÷ theoretical) × 100.
  2. Usually less than 100% in practice.
  3. Reasons: reversible reactions, side reactions, practical losses.
  4. High yield = less waste, lower cost, more sustainable.

Photograph this card. Tomorrow, cover it and say each line first.

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