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AQA Chemistry 5.4.1.1–5.4.1.2

Reactivity of metals and metal oxides

Drop metals into water, acid and each other’s solutions. Build the order from what you see, then use one idea to explain it all: how readily a metal forms positive ions.

Start here

A gold ring and an old bike.

Gold jewellery dug up after hundreds of years still shines. An iron bike left out for one wet winter goes orange-brown with rust.

If you had to guess, which metal reacts more easily?

Metals and oxygen

Gaining oxygen is oxidation.

Metals react with oxygen to produce metal oxides. These are oxidation reactions because the metal gains oxygen. The reverse, losing oxygen, is reduction.

magnesium + oxygenmagnesium oxidemagnesium is oxidised

Metal oxides are bases: they neutralise acids.

Bench · water and dilute acid, at room temperature

Watch each metal, then rank it.

Same-sized pieces, one liquid at a time. Test all eight metals; each joins the ladder once you have seen it react.

Pick a metal

Start with potassium in water.

metal + watermetal hydroxide + hydrogenmetal + acidsalt + hydrogen

When a metal reacts, its atoms form positive ions. The reactivity of a metal is related to its tendency to form positive ions: the more readily it does, the more vigorous the reaction. Compare metals on the same reaction, with same-sized pieces.

Displacement · predict, then look

A more reactive metal pushes out a less reactive one.

Put a metal strip in a solution of another metal’s salt. If the strip is more reactive, it displaces the other metal, which coats the strip. Choose a pair and predict.

Metal strip

Solution

Will it react?

0 of 3 predictions

Higher · ionic equations and electrons

Combined Higher

Oxidation is the loss of electrons and reduction is the gain of electrons. Write displacement as an ionic equation: the sulfate ions do not change, so they are left out.

Fe + Cu2+Fe2+ + Cu
  • Each iron atom loses 2 electrons to become Fe2+: iron is oxidised.
  • Each Cu2+ ion gains 2 electrons to become a copper atom: Cu2+ is reduced.

Think again · which way round

“Any metal can push another metal out of its solution.”

Your call

Predict

A copper strip is put into iron sulfate solution. What happens?

Sort

Reaction or no reaction?

Place each mixture, at room temperature.

Tap a card, then tap the box it belongs in. Tap a placed card to take it back.

Command words in this lesson

Deduce
Put metals in order from the results you are given.
Predict
Say whether it reacts, using the positions in the series.
Explain
Link reactivity to the tendency to form positive ions.

Key fact

The reactivity of a metal is related to its tendency to form positive ions. A more reactive metal displaces a less reactive metal from its compounds.

Key note · AQA 5.4.1.1–5.4.1.2

Reactivity of metals

  1. Metals react with oxygen to produce metal oxides: oxidation, because the metal gains oxygen. Reduction is the loss of oxygen.
  2. Reactivity series: potassium, sodium, lithium, calcium, magnesium, aluminium, (carbon), zinc, iron, (hydrogen), copper, silver, gold.
  3. With water and dilute acid at room temperature, more reactive metals react more vigorously. Copper does not react with dilute acid.
  4. When metals react, their atoms form positive ions. Reactivity is related to the tendency to form positive ions.
  5. A more reactive metal displaces a less reactive metal from a solution of its salt.
  6. Higher: oxidation is loss of electrons, reduction is gain. In Fe + Cu²⁺, iron is oxidised and Cu²⁺ is reduced.

Photograph this card. Tomorrow, cover it and say each line first.

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