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๐Ÿงช The pH Scale and Neutralisation

Spec 5.4.2.4 ๐Ÿ“— Foundation
๐Ÿ“– In-Depth Theory

The pH Scale

The pH SCALE measures the CONCENTRATION of hydrogen ions (Hโบ) in a solution โ€” it indicates how acidic or alkaline a solution is.
Scale range: 0 to 14 (though values slightly outside this range are possible).
pH 0โ€“6: ACIDIC (more Hโบ ions than OHโป ions)
pH 7: NEUTRAL (equal Hโบ and OHโป โ€” pure water at 25ยฐC)
pH 8โ€“14: ALKALINE (more OHโป ions than Hโบ ions)
The pH scale is LOGARITHMIC โ€” each unit change represents a 10ร— change in Hโบ concentration:
pH 3 has 10ร— more Hโบ than pH 4.
pH 3 has 100ร— more Hโบ than pH 5.
Typical pH values:
Hydrochloric acid (conc.): pH ~0โ€“1
Vinegar (ethanoic acid): pH ~3
Coffee: pH ~5
Pure water: pH 7
Baking soda solution: pH ~9
Sodium hydroxide solution: pH ~13โ€“14

Indicators and Measuring pH

An INDICATOR is a substance that changes colour depending on the pH of a solution.
UNIVERSAL INDICATOR:
A mixture of indicators that shows a range of colours across the pH scale.
Red โ†’ orange โ†’ yellow โ†’ green โ†’ blue โ†’ purple as pH increases from 0 to 14.
Gives an APPROXIMATE pH โ€” tells you the pH range.
LITMUS:
Red in ACID, blue in ALKALI, purple in neutral.
Simple test โ€” tells you acid or alkali, not the pH number.
PHENOLPHTHALEIN:
Colourless in acid, PINK in alkali.
Used in titrations โ€” clear colour change at the end point.
pH PROBE / METER:
Gives a PRECISE numerical pH reading โ€” more accurate than indicators.
Used in industry and for accurate laboratory measurements.
THE RELATIONSHIP BETWEEN pH AND CONCENTRATION:
The MORE Hโบ ions in solution โ†’ LOWER pH (more acidic).
The MORE OHโป ions in solution โ†’ HIGHER pH (more alkaline).
Adding water DILUTES the solution โ†’ concentration of Hโบ decreases โ†’ pH INCREASES towards 7.

Effect of Neutralisation on pH

Adding a BASE to an ACID gradually increases the pH (makes it less acidic).
Adding an ACID to an ALKALI gradually decreases the pH (makes it less alkaline).
A TITRATION CURVE shows how pH changes as acid is added to alkali:
At the START: pH high (~13) โ€” the solution is strongly alkaline.
As acid is added: pH falls slowly at first.
Near the END POINT: pH drops RAPIDLY โ€” a large pH change for a small addition.
At the END POINT: pH = 7 (if strong acid + strong alkali).
After the end point: pH continues to fall as excess acid is added.
WHY SUCH A SHARP CHANGE NEAR THE END POINT:
Near the equivalence point, there is very little OHโป left to absorb the Hโบ from the added acid.
So each small addition of acid produces a large change in Hโบ concentration โ†’ large pH change.
โš ๏ธ Common Mistake

Lower pH = MORE ACIDIC = MORE Hโบ ions. Higher pH = MORE ALKALINE = FEWER Hโบ ions (more OHโป). Students often confuse pH 2 and pH 12 โ€” pH 2 is strongly acidic, pH 12 is strongly alkaline. pH 7 is neutral โ€” pure water. NOT all solutions at pH 7 are water.

๐Ÿ“Œ Key Note

pH 0โ€“6: acidic. pH 7: neutral. pH 8โ€“14: alkaline. Lower pH = more Hโบ ions. pH scale is logarithmic โ€” each unit = 10ร— change in Hโบ. Universal indicator: shows range of colours. Phenolphthalein: colourless in acid, pink in alkali. pH meter: most accurate.

๐ŸŽฏ Matching Activity โ€” Match the pH to the Description

Match each pH value to the correct description. โ€” drag the symbols on the right to match the component names on the left.

pH 1
Drop here
pH 7
Drop here
pH 13
Drop here
pH 4
Drop here
pH 10
Drop here
Weakly acidic โ€” e.g. black coffee or tomato juice
Neutral โ€” equal Hโบ and OHโป ions โ€” pure water at 25ยฐC
Weakly alkaline โ€” e.g. baking soda solution
Strongly acidic โ€” high concentration of Hโบ ions
Strongly alkaline โ€” high concentration of OHโป ions
๐ŸŽฏ Test Yourself
Question 1 of 2
1. A solution has a pH of 2. Another has a pH of 4. How do their Hโบ ion concentrations compare?
2. An acid is diluted by adding water. What happens to its pH?
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